Find the most up-to-date version of ASTM E at Engineering Buy ASTM E GUIDE FOR QUANTITATIVE ANALYSIS BY ENERGY- DISPERSIVE SPECTROSCOPY from SAI Global. Standard Guide for Quantitative Analysis by Energy-Dispersive Spectroscopy. Status: Withdrawn · Replaced by: ASTM E Buy this standard. Price: SEK.
|Published (Last):||28 February 2007|
|PDF File Size:||11.32 Mb|
|ePub File Size:||7.20 Mb|
|Price:||Free* [*Free Regsitration Required]|
The actual accelerating voltage of the electron beam does not always correspond with the voltage selected on the instrument. Consequently, ee1508 would expect the most improvement using a phi-rho-z method in light element analysis.
The result is a peak at 1. Practice E is used to analyze the round-robin data for consistency and calculates intralaboratory repeatability and interlaboratory reproducibility statistics. There was also a severe overlap between the M lines of tantalum and tungsten. As such, the precision obtained should be representative of the technique. The report should also specify whether standards or standardless methods were used, what matrix corrections were applied, and whether any elemental concentrations were calculated by difference or by stoichiometry.
The differences in the results each produces are usually much less than the precision of the analysis. For the alloy MAasm average was 3. Carbon that appears to be tan in color on the specimen surface, or on a piece of?
ASTM B r Working distance is measured in the microscope; its accuracy depends on the method used to measure it and the specimen position. Light Element Analysis For a more detailed treatment of the subject, see Goldstein, et al. The s count speci? If the specimen is inhomogeneous at the micrometre level, then a truly quantitative analysis is not possible, and a bulk technique such as X-ray?
Last previous edition approved in as E — Windowless detectors approach the theoretical highest efficiency of the detecting crystal, but in the open position contaminants in axtm sample chamber are free to condense on the cold crystal.
ASTM E1508 – 12a
With trace elements, and especially with peak overlaps among trace elements, precision is signi? If the stoichiometry of compounds containing light elements is known, then calculation by stoichiometry is the most accurate method.
It should also be of similar composition and thickness between the standards and the unknowns. For many metals containing medium atomic number elements, 20 to 30 kV is a good choice. A spectrum from pure aluminum could be collected followed by pure copper in the same spectrum. The alloy contained both asmt and low atomic number elements necessitating the use of K, L, and M lines.
Accordingly, most operators choose a 0—10 keV display at higher display resolution rather than a 0—20 keV display at lower resolution. The nominal composition of each specimen was also included for reference.
Current edition approved Nov. The larger the active area of the detector, the more counts aatm be collected, but at the expense of spectral resolution. Some software also allows the operator to? Standardless methods were about equivalent to those using standards for this specimen. Two approaches to this problem commonly used in commercial systems are background modeling and digital?
Standard Guide for Quantitative Analysis by Energy-Dispersive Spectroscopy
Spectrometer distance is the horizontal distance from the spectrometer to the beam; it is measured using the scale provided by the manufacturer on the spectrometer slide. EDS detectors do not resolve all peaks. However, two artifacts that are commonly seen are pulse pileup peaks and silicon escape peaks.
Clearly, for a given overall counting time, the relative precision associated with major elements is greater than for minor or trace elements, insofar as there are necessarily fewer counts in minor peaks.
The presence of eight elements also added to the difficulty in analyzing this material. Referenced Documents purchase separately The documents listed below are referenced within the subject standard but are not provided f1508 part of the standard.
Most sources of bias are either insigni? For materials such as minerals and ceramics, which contain light elements that is, of low atomic number15 kV is usually a good compromise.
Note that these requirements for surface preparation preclude the quantitative analysis of casual samples, such as unpolished surfaces like fracture surfaces.
Quantitative light element e11508 is less precise than that of heavier elements, because the count rate of soft E158 rays is lower. Software is usually available to calibrate the EDS system, and one should consult the system manual for the asym of operation. Defocusing the beam or scanning it over an area of varying composition does not provide an average composition, because the e11508 factors applied to the intensity ratio are themselves a function of composition.
Even though one cannot see the individual components of a peak adtm in a spectrum, there are computer methods of deconvolution. On the MA alloy, the reproducibility among laboratories was much less than that of the standards technique R in Table 4.
ASTM E – 12a Standard Guide for Quantitative Analysis by Energy-Dispersive Spectroscopy
A number in parentheses indicates the year of last reapproval. The alloy MA specimen was selected because of its inherent homogeneity and because it presented several analytical problems. Although results of the standardless analyses were rather good on the Type stainless steel, they may be considerably inferior on other types of specimens.
It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Historical Version s – view previous versions of standard. In this situation use of a different analytical line may be possible, or if not, a technique with higher spectral resolution such as wavelength dispersive spectrometry is indicated.